[Ba13Sb36Cl34O54]8-: high-nuclearity cluster for the assembly of nanocluster-based compounds

Zhao-Feng Wu; Bing Hu; Zhi-Hua Fu; Hao Wang; Gang Xu; Liao-Kuo Gong; Guo-Dong Zou; Xiao-Ying Huang; Jing Li

doi:10.1039/c9cc02145k

[Ba₁₃Sb₃₆Cl₃₄O₅₄]^8-: high-nuclearity cluster for the assembly of nanocluster-based compounds

Chem Commun (Camb). 2019 Jul 4;55(52):7442-7445. doi: 10.1039/c9cc02145k. Epub 2019 Jun 5.

Authors

Zhao-Feng Wu¹, Bing Hu², Zhi-Hua Fu², Hao Wang³, Gang Xu², Liao-Kuo Gong⁴, Guo-Dong Zou⁵, Xiao-Ying Huang², Jing Li³

Affiliations

¹ State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. hubing@fjirsm.ac.cn xyhuang@fjirsm.ac.cn and Department of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, NJ 08854, USA. jingli@rutgers.edu.
² State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. hubing@fjirsm.ac.cn xyhuang@fjirsm.ac.cn.
³ Department of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, NJ 08854, USA. jingli@rutgers.edu.
⁴ State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. hubing@fjirsm.ac.cn xyhuang@fjirsm.ac.cn and University of Chinese Academy of Sciences, Beijing 100049, P. R. China.
⁵ College of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang, Henan 464000, P. R. China.

PMID: 31165815
DOI: 10.1039/c9cc02145k

Abstract

Herein, we report two nanocluster-based compounds built on an unprecedented cluster [Ba₁₃Sb₃₆Cl₃₄O₅₄]^8-, which represents the first example of a discrete alkaline earth (AE)-containing oxochloride cluster and the largest Sb-based oxohalide cluster to date; the proton-conducting property of the compounds was investigated.