Rapid quantitative analysis of adulterated rice with partial least squares regression using hyperspectral imaging system

J Sci Food Agric. 2019 Sep;99(12):5558-5564. doi: 10.1002/jsfa.9824. Epub 2019 Jun 26.

Abstract

Background: Rice adulteration in the food industry that infringes on the interests of consumers is considered very serious. To realize the rapid and precise quantitation of adulterated rice, a visible near infrared (VNIR) hyperspectral imaging system (380-1000 nm) was developed in the present study. A Savitsky-Golay first derivative (SG1) transform was utilized to eliminate the constant spectral baseline offset. Then, the adulterated levels of rice samples were quantified by partial least squares regression (PLSR).

Results: A SG1-PLSR model based on full-wavelength was attained with a coefficient of determination of prediction set (RP ) of 0.9909, root-mean-square error of prediction set (RMSEP ) of 0.0447 g kg-1 and residual predictive deviation (RPDP ) of 11.28. Furthermore, fifteen important wavelengths were selected based on the weighted regression coefficients (BW ) and a simplified model (PLSR-15) was established with RP of 0.9769, RMSEP of 0.0708 g kg-1 and RPDP of 3.49. Finally, two visualization maps produced by applying the optimal models (SG1-PLSR and PLSR-15) were used to visualize the adulterated levels of rice.

Conclusion: These results demonstrate that VNIR hyperspectral imaging system is an effective tool for rapidly quantifying and visualizing the adulterated levels of rice. © 2019 Society of Chemical Industry.

Keywords: PLSR; adulterated rice; hyperspectral imaging; visualization map.

Publication types

  • Evaluation Study

MeSH terms

  • Food Contamination / analysis
  • Least-Squares Analysis
  • Oryza / chemistry*
  • Spectroscopy, Near-Infrared / methods*