Secondary organic aerosol formation from styrene photolysis and photooxidation with hydroxyl radicals

Abstract

The formation of secondary organic aerosol (SOA) generated by irradiating styrene in the presence and/or absence of OH, NOx, H₂O vapour and seed aerosol has been investigated for the first time. Experiments were conducted in a smog chamber at 298 K and atmospheric pressure. Styrene decay was measured by gas chromatography with a mass spectrometric detector (GC-MS), and the temporal evolution of the aerosol was monitored using a fast mobility particle sizer (FMPS). The SOA yield increases as the initial styrene concentration increases, leading to yields ranging from 1.8% to 3.5% for styrene photolysis, and from 2.4% to 5.0% for its photooxidation. In both cases, the organic aerosol formation can be expressed by a one-product gas/particle partitioning absorption model. The particle number concentration, mass and yield decrease in the presence of NOx and seed aerosol but increase at higher relative humidity (RH). The gas phase and SOA composition were analysed offline using a filter/denuder sampling system simultaneously collecting gas- and particle-phase products. Benzaldehyde was confirmed as the main gas-phase product of the reaction. However, although products in the particle phase were detected, they could not be identified. Moreover, the aqueous filter extracts were analysed using UV-Visible spectrophotometry to determine differences in the optical properties of SOA produced in the presence and absence of NOx. The results from this work may be used to discuss the implications of atmospheric SOA generation from styrene degradation.