The applicability of compost, zeolite and calcium oxide in assisted remediation of acidic soil contaminated with Cr(III) and Cr(VI)

Environ Sci Pollut Res Int. 2019 Jul;26(21):21351-21362. doi: 10.1007/s11356-019-05221-y. Epub 2019 May 23.

Abstract

The effect of soil amendments, i.e., compost, zeolite, and calcium oxide, on the chemical properties of soil contaminated with Cr(III) and Cr(VI) and the uptake of selected heavy metals by spring barley (Hordeum vulgare L.) and maize (Zea mays L.) was determined in a pot experiment. The content of all investigated heavy metals in the tested plants varied significantly in response to the tested soil amendments and increasing concentrations of Cr(III) and Cr(VI). Compost, zeolite, and calcium oxide contributed to an increase in the average yield of the aerial parts of maize plants only in treatments contaminated with Cr(III). The concentrations of Cr, Zn, and Ni in the aerial parts of spring barley and maize were higher in treatments contaminated with Cr(III) than in treatments contaminated with Cr(VI). Calcium oxide induced a significant increase in soil pH relative to the control treatment. In treatments without soil amendments, the average Cr content of soil was higher in pots contaminated with Cr(VI). The concentrations of Zn and Cu in non-amended treatments were negatively correlated with increasing doses of Cr(III) and Cr(VI). Calcium oxide decreased the average content of Cr, Cu, and Ni in all experimental variants. Compost increased the average content of Zn in treatments contaminated with Cr(III) and Cr(IV) relative to non-amended soil.

Keywords: Calcium oxide; Chromium contamination; Compost; Soil amendments; Zeolite.

MeSH terms

  • Calcium Compounds
  • Chromium / analysis*
  • Composting / methods*
  • Environmental Restoration and Remediation / methods*
  • Hordeum
  • Oxides
  • Soil / chemistry
  • Soil Pollutants / analysis*
  • Zea mays
  • Zeolites / chemistry

Substances

  • Calcium Compounds
  • Oxides
  • Soil
  • Soil Pollutants
  • Chromium
  • Zeolites
  • chromium hexavalent ion
  • lime