Polymer Electrolyte Membranes Based on Nafion and a Superacidic Inorganic Additive for Fuel Cell Applications

Lucia Mazzapioda; Stefania Panero; Maria Assunta Navarra

doi:10.3390/polym11050914

Polymer Electrolyte Membranes Based on Nafion and a Superacidic Inorganic Additive for Fuel Cell Applications

Polymers (Basel). 2019 May 22;11(5):914. doi: 10.3390/polym11050914.

Authors

Lucia Mazzapioda¹, Stefania Panero², Maria Assunta Navarra³

Affiliations

¹ Department of Chemistry, Sapienza University of Rome. Piazzale Aldo Moro 5, 00185 Rome, Italy. lucia.mazzapioda@uniroma1.it.
² Department of Chemistry, Sapienza University of Rome. Piazzale Aldo Moro 5, 00185 Rome, Italy. stefania.panero@uniroma1.it.
³ Department of Chemistry, Sapienza University of Rome. Piazzale Aldo Moro 5, 00185 Rome, Italy. mariassunta.navarra@uniroma1.it.

Abstract

Nafion composite membranes, containing different amounts of mesoporous sulfated titanium oxide (TiO₂-SO₄) were prepared by solvent-casting and tested in proton exchange membrane fuel cells (PEMFCs), operating at very low humidification levels. The TiO₂-SO₄ additive was originally synthesized by a sol-gel method and characterized through x-ray diffraction (XRD), scanning electron microscopy (SEM), thermogravimetric analysis (TGA) and ion exchange capacity (IEC). Peculiar properties of the composite membranes, such as the thermal transitions and ion exchange capacity, were investigated and here discussed. When used as an electrolyte in the fuel cell, the composite membrane guaranteed an improvement with respect to bare Nafion systems at 30% relative humidity and 110 °C, exhibiting higher power and current densities.

Keywords: PEM fuel cells; mesoporous sulfated titania; nanocomposite polymer electrolytes.