Surface nanobubbles on the rare earth fluorcarbonate mineral synchysite

J Colloid Interface Sci. 2019 Sep 15:552:66-71. doi: 10.1016/j.jcis.2019.05.014. Epub 2019 May 6.

Abstract

Surface nanobubbles have been identified to play an important role in a range of industries from mineral processing to food science. The formation of surface nanobubbles is of importance for mineral processing in the extraction of complex ores, such as those containing rare earth elements. This is due to the way minerals are extracted utilising froth flotation. In this study, surface nanobubbles were imaged using non-contact atomic force microscopy on a polished cross section containing rare earth minerals. Nanobubbles were found on synchysite under reagent conditions expected to induce hydrophobicity in rare earth minerals, which is required for efficient processing. Synchysite -(Ce) is a rare earth fluorcarbonate mineral containing over 30% rare earth elements. Relatively little research has been conducted on synchysite, with only a few papers on its surface behaviour and flotation. The resulting nanobubbles were analysed and showed an average contact angle of 24° ± 8. These are in line with contact angles found on dolomite and galena by previous studies.

Keywords: Bastnäsite; Carbonatite; Fluorcarbonate; Non-contact atomic force microscopy; Rare earth elements; Surface nanobubbles; Synchysite.