An exceptionally stable core-shell MOF/COF bifunctional catalyst for a highly efficient cascade deacetalization-Knoevenagel condensation reaction

Ming-Liang Gao; Mei-Hong Qi; Lin Liu; Zheng-Bo Han

doi:10.1039/c9cc02174d

An exceptionally stable core-shell MOF/COF bifunctional catalyst for a highly efficient cascade deacetalization-Knoevenagel condensation reaction

Chem Commun (Camb). 2019 May 30;55(45):6377-6380. doi: 10.1039/c9cc02174d.

Authors

Ming-Liang Gao¹, Mei-Hong Qi, Lin Liu, Zheng-Bo Han

Affiliation

¹ College of Chemistry, Liaoning University, Shenyang 110036, P. R. China. ceshzb@lnu.edu.cn liulin@lnu.edu.cn.

PMID: 31089619
DOI: 10.1039/c9cc02174d

Abstract

A novel strategy has been developed to construct a highly stable core-shell MOF@COF (PCN-222-Co@TpPa-1) bifunctional catalyst through strong π-π stacking interaction. This hybrid material with spatially isolated antagonistic acid-base sites can effectively catalyze the deacetalization-Knoevenagel condensation cascade reaction.