A Crosslinked Soybean Protein Isolate Gel Polymer Electrolyte Based on Neutral Aqueous Electrolyte for a High-Energy-Density Supercapacitor

Polymers (Basel). 2019 May 13;11(5):863. doi: 10.3390/polym11050863.

Abstract

A crosslinked membrane based on renewable, degradable and environmentally friendly soybean protein isolate was formed by solution casting method. A series of gel polymer electrolytes were prepared with the crosslinked membranes saturated with 1 mol·L-1 Li2SO4. The solid-state electric double-layer capacitors were fabricated with the prepared gel polymer electrolytes and activated carbon electrodes. The optimized solid-state supercapacitor delivered a single electrode specific capacitance of 115.17 F·g-1 at a current density of 1.0 A·g-1, which was higher than the supercapacitor assembled with the commercial separator in 1 mol·L-1 Li2SO4. The solid-state supercapacitor exhibited an outstanding cycling stability, indicating that the gel polymer electrolyte based on the crosslinked soybean protein isolate membrane could be a promising separator for a solid-state supercapacitor.

Keywords: crosslinked membranes; gel polymer electrolyte; solid-state supercapacitor; soybean protein isolate.