Manufacturing large-area devices through a low-cost and large batch printing technique is the key to the commercialization of organic solar cells (OSCs). However, the lack of printable anode interlayer (AIL) materials severely impedes the development of high-efficiency printed OSCs. Herein, we synthesize three p-type self-doped conjugated polyelectrolytes (CPEs), namely, PCP-B, PCP-2B, and PCP-3B, as printable AIL materials for fabricating high-performance and large-area OSCs. By increasing the number of benzene units in the polymer backbone, the work function of the CPEs was enhanced from 4.57 to 5.01 eV, and the optical transparency was also improved because of the enlarged polymer band gap. The improved photoelectronic properties as well as a good film-forming capacity make the PCP-3B an ideal AIL material to be processed by the printing technique. By using PCP-3B, a 1 cm2 printed device was fabricated in which all the functional layers, including the AIL, active layer, and cathode interlayer were processed by blade-coating, achieving a power conversion efficiency (PCE) of 9.67%. The PCE belongs to the highest efficiency at present for printable large-area OSCs, showing a promising prospect for the OSC mass production.
Keywords: large-area device; printed organic solar cell; self-doping property; transparency; work function.