Determination of the Leaching Potential and Residues Activity of Imidazolinone Herbicide in Clearfield Rice Soil Using High-Performance Liquid Chromatography

Bull Environ Contam Toxicol. 2019 Aug;103(2):348-353. doi: 10.1007/s00128-019-02625-x. Epub 2019 May 8.

Abstract

The residual activity of herbicides may be detrimental to the environment, requiring analysis of the persistent residues in the soil and water. A field study was conducted to measure the residues of Imidazolinone (IMI) in three Clearfield® rice field soils at three different locations in Malaysia. The analyses of IMI in the soil samples were carried out using a high-performance liquid chromatography (HPLC). These herbicides are widely used; however, few studies have been conducted on both residues, especially in the context of Malaysian soil. Residues of imazapic and imazapyr were found to fall within 0.03-0.58 µg/mL and 0.03-1.96 µg/mL, respectively, in three locations. IMI herbicides are persistent in the soil, and their residues remain for up to 85 days after application. A pre-harvest study was suggested for these herbicides on water, which will provide a clearer indicator on the use of IMI in Clearfield® rice fields.

Keywords: Chromatography; HPLC; Herbicides; Imazapic; Imazapyr.

MeSH terms

  • Chromatography, High Pressure Liquid / methods
  • Environmental Monitoring / methods
  • Herbicides / analysis*
  • Imidazoles / analysis*
  • Malaysia
  • Oryza / growth & development*
  • Pesticide Residues / analysis*
  • Soil / chemistry*
  • Soil Pollutants / analysis*

Substances

  • Herbicides
  • Imidazoles
  • Pesticide Residues
  • Soil
  • Soil Pollutants