Sodium batteries (SBs) have aroused increasing attention due to the abundance and low cost of elemental sodium. In recent decades, intensive efforts have been under way to exploit advanced SBs for practical applications. However, conventional liquid electrolytes used in SBs suffer from serious safety hazards (high volatility, inflammability, and leakage), severe side reactions between electrodes and electrolytes, and inevitable sodium dendrite problems, which are greatly detrimental to battery performance. Notably, polymer electrolytes are recognized as the optimal solution to resolve the above-mentioned bottlenecks. Herein, we mainly summarize a series of polymer electrolytes based on polymers containing ethoxylated units, poly(vinylidene fluoride-hexafluoropropylene) (P(VDF-HFP)), poly(methyl methacrylate) (PMMA), polyacrylonitrile (PAN), poly(vinylpyrrolidone) (PVP), single-ion conductors, polysaccharides, and so on. Notably, this review demonstrates the natural merits of polymer electrolytes for SBs (such as high safety, suppression of sodium dendrite formation, and reduced electrolyte decomposition), presents the requirements for ideal polymer electrolytes for the first time, and provides concrete discussions into recent progress of various polymer electrolytes as well. Furthermore, potential challenges and perspectives of polymer electrolytes for advanced SBs are also envisioned at the end of this review. Overall, we hope this discussion will make sense to resolve fundamental research and practical issues of polymer electrolytes for advanced SBs.
Keywords: natural merits; polymer electrolytes; recent progresses; safety; sodium batteries.