Orange peel valorization by pyrolysis under the carbon dioxide environment

Abstract

To valorize biomass waste, pyrolysis of orange peel was mainly investigated as a case study. In an effort to establish a more sustainable thermolytic platform for orange peel, this study particularly employed CO₂ as reactive gas medium. Accordingly, this study laid great emphasis on elucidating the mechanistic role of CO₂ in pyrolysis of orange peel. The thermo-gravimetric analysis (TGA) confirmed that no occurrence of the heterogeneous reactions between the solid sample and CO₂. However, the gaseous effluents from pyrolysis of orange peel experimentally proved that CO₂ effectively suppressed dehydrogenation of volatile matters (VMs) evolved from the thermolysis of orange peel by random bond scissions. Moreover, CO₂ reacted VMs, thereby resulting in the formation of CO. Note that the formation of CO was being initiated at temperatures ≥550 °C. The two identified roles of CO₂ led to the compositional modification of pyrolytic oil by means of lowering aromaticity.

Keywords: CO(2); Orange peel; Pyrolysis; Syngas; Valorization; Waste-to-energy.