Facile synthesis of ternary graphene nanocomposites with doped metal oxide and conductive polymers as electrode materials for high performance supercapacitors

Saira Ishaq; Mahmoud Moussa; Farah Kanwal; Muhammad Ehsan; Muhammad Saleem; Truc Ngo Van; Dusan Losic

doi:10.1038/s41598-019-41939-y

Facile synthesis of ternary graphene nanocomposites with doped metal oxide and conductive polymers as electrode materials for high performance supercapacitors

Sci Rep. 2019 Apr 12;9(1):5974. doi: 10.1038/s41598-019-41939-y.

Authors

Saira Ishaq^{1

2

3}, Mahmoud Moussa^{2

3}, Farah Kanwal¹, Muhammad Ehsan¹, Muhammad Saleem¹, Truc Ngo Van^{2

3}, Dusan Losic^{4

5}

Affiliations

¹ Institute of Chemistry, University of the Punjab, Lahore, 54590, Pakistan.
² School of Chemical Engineering, University of Adelaide, Adelaide, 5005, SA, Australia.
³ ARC Research Hub for Graphene Enabled Industry Transformation, The University of Adelaide, Adelaide, 5005, SA, Australia.
⁴ School of Chemical Engineering, University of Adelaide, Adelaide, 5005, SA, Australia. dusan.losic@adelaide.edu.au.
⁵ ARC Research Hub for Graphene Enabled Industry Transformation, The University of Adelaide, Adelaide, 5005, SA, Australia. dusan.losic@adelaide.edu.au.

Abstract

Supercapacitors (SCs) due to their high energy density, fast charge storage and energy transfer, long charge discharge curves and low costs are very attractive for designing new generation of energy storage devices. In this work we present a simple and scalable synthetic approach to engineer ternary composite as electrode material based on combination of graphene with doped metal oxides (iron oxide) and conductive polymer (polypyrrole) with aims to achieve supercapacitors with very high gravimetric and areal capacitances. In the first step a binary composite with graphene mixed with doped iron oxide (rGO/MeFe₂O₄) (Me = Mn, Ni) was synthesized using new single step process with NaOH acting as a coprecipitation and GO reducing agent. This rGO/MnFe₂O₄ composite electrode showed gravimetric capacitance of 147 Fg^-1 and areal capacitance of 232 mFcm^-2 at scan rate of 5 mVs^-1. In the final step a conductive polypyrrole was included to prepare a ternary composite graphene/metal doped iron oxide/polypyrrole (rGO/MnFe₂O₄/Ppy) electrode. Ternary composite electrode showed significantly improved gravimetric capacitance and areal capacitance of 232 Fg^-1 and 395 mFcm^-2 respectively indicating synergistic impact of Ppy additives. The method is promising to fabricate advanced electrode materials for high performing supercapacitors combining graphene, doped iron oxide and conductive polymers.