Hyper-crosslinked (HCL) polystyrenes show outstanding properties, such as high specific surface area and adsorption capability. Several researches have been recently focused on tailoring their performance for specific applications, such as gas adsorption and separation, energy storage, air and water purification processes, and catalysis. In this review, main strategies for the realization of HCL polystyrene-based materials with advanced properties are reported, including a summary of the synthetic routes that are adopted for their realization and the chemical modification approaches that are used to impart them specific functionalities. Moreover, the most up to date results on the synthesis of HCL polystyrene-based nanocomposites that are realized by embedding these high surface area polymers with metal, metal oxide, and carbon-based nanofillers are discussed in detail, underlining the high potential applicability of these systems in different fields.
Keywords: adsorption properties; high specific surface area; hyper-crosslinked nanocomposites; hyper-crosslinked polystyrene; microporous materials.