Use of Bacterial Cellulose and Crosslinked Cellulose Nanofibers Membranes for Removal of Oil from Oil-in-Water Emulsions

Polymers (Basel). 2017 Aug 23;9(9):388. doi: 10.3390/polym9090388.

Abstract

Abstract: Never-dried bacterial cellulose (BC) and crosslinked cellulose nanofibers (CNF) were used for the removal of oil from stabilized and non-stabilized oil-in-water emulsions with droplet sizes less than 1 µm. The CNF membranes were exchanged with isopropyl alcohol before drying. The microscopic structure of the prepared membranes was evaluated using scanning electron microscopy (SEM); the water flux and the rejection of oil were evaluated using a dead-end filtration cell. BC harvested after different incubation time periods (2 to 10 days) did not show a change in the width of the nanofibers, but only the thickness of the membranes was increased. Pure water flux was not affected as a result of increasing thicknesses of BC membranes harvested after 4⁻10 days while BC harvested after two days had significantly higher water flux than the others. BC showed a higher flux and efficiency in removing oil from oil emulsions than CNF membranes. Removal of oil by the different membranes from the non-stabilized oil emulsion was more efficient than from the stabilized one.

Keywords: Keyword: bacterial cellulose; cellulose nanofibers; membranes; oil emulsion; palm fruit stalks.