Four novel choline carboxylate aqueous solution systems were developed by mixing H₂O with choline nicotinate [Ch][Na], choline ferulate [Ch][Fa], choline vanillate [Ch][Va] and choline syringate [Ch][Sa]. The solubility of lignin in the four solvents was determined at 25 °C. The influence of the molar ratio of H₂O to [Ch][Na] ([Ch][Fa], [Ch][Va] and [Ch][Sa]) and the anionic structure on lignin solubility were systematically investigated. It was found that, the anionic structure and H₂O content significantly affected lignin dissolution. Interestingly, H₂O/[Ch][Na] and H₂O/[Ch][Fa] solvents show efficient capacity for lignin dissolution even at room temperatures. The dissolution of lignin in H₂O/[Ch][Na] and H₂O/[Ch][Fa] solvents is mainly ascribed to the interaction of lignin with the alkyl chain in the anion and cation dissociated from [Ch][Na]([Ch][Fa]) by H₂O. In addition, the recycling of the lignin solvent was examined, and the structure and thermostability of the lignin regenerated from the solvent were also estimated.
Keywords: H2O/choline carboxylate solvent; dissolution mechanism; lignin; recycling; regenerated lignin properties.