Flexural Behavior and Fracture Mechanisms of Short Carbon Fiber Reinforced Polyether-Ether-Ketone Composites at Various Ambient Temperatures

Bing Zheng; Tianzhengxiong Deng; Maoyuan Li; Zhigao Huang; Huamin Zhou; Dequn Li

doi:10.3390/polym11010018

Flexural Behavior and Fracture Mechanisms of Short Carbon Fiber Reinforced Polyether-Ether-Ketone Composites at Various Ambient Temperatures

Polymers (Basel). 2018 Dec 23;11(1):18. doi: 10.3390/polym11010018.

Authors

Bing Zheng¹, Tianzhengxiong Deng², Maoyuan Li³, Zhigao Huang⁴, Huamin Zhou⁵, Dequn Li⁶

Affiliations

¹ State Key Laboratory of Material Processing and Die & Mold Technology, Huazhong University of Science and Technology, Wuhan 430074, China. zhengbing@hust.edu.cn.
² State Key Laboratory of Material Processing and Die & Mold Technology, Huazhong University of Science and Technology, Wuhan 430074, China. uezuuezu@hust.edu.cn.
³ State Key Laboratory of Material Processing and Die & Mold Technology, Huazhong University of Science and Technology, Wuhan 430074, China. limaoyuan@hust.edu.cn.
⁴ State Key Laboratory of Material Processing and Die & Mold Technology, Huazhong University of Science and Technology, Wuhan 430074, China. huangzhigao@hust.edu.cn.
⁵ State Key Laboratory of Material Processing and Die & Mold Technology, Huazhong University of Science and Technology, Wuhan 430074, China. hmzhou@hust.edu.cn.
⁶ State Key Laboratory of Material Processing and Die & Mold Technology, Huazhong University of Science and Technology, Wuhan 430074, China. ldq@hust.edu.cn.

Abstract

In this study, the flexural behavior and fracture mechanisms of short carbon fiber reinforced polyether-ether-ketone (SCFR/PEEK) composites at various ambient temperatures were investigated. First, the crystallinity and glass transition temperature (T_g) of PEEK and SCFR/PEEK were analyzed by differential scanning calorimetry analysis and dynamic mechanical analysis tests, respectively. The addition of SCFs increases the T_g but does not change the crystallinity of the PEEK matrix. Then, the three-point flexural tests of PEEK and SCFR/PEEK were performed over the temperature range of 20 to 235 °C, and the temperature-dependencies of the flexural properties of PEEK and SCFR/PEEK were discussed in detail. Finally, the microstructure of SCFR/PEEK was observed using a digital microscope and scanning electron microscope. The results show that the tension crack occurs first, and the crack extends upward leading to the shear crack and compression crack at room temperature. The fracture of SCFR/PEEK is mainly due to the extraction and rupture of SCFs. At high temperatures (above T_g), the tension crack and compression crack both occur, and the strong ductility of the matrix prevents the generation of shear crack. The fracture of SCFR/PEEK is mainly due to the rotation and extraction of SCFs, while the SCFs rupture plays a minor role.

Keywords: PEEK; SCF; flexural behavior; fracture mechanisms; microstructure; thermal properties.

Abstract

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