Paper, with advantages of low-cost, easy fabrication and disposal, flexibility and renewability, is a suitable substrate material for various applications. Functionalization and patterning on paper substrates are commonly required in many applications. Although many methods have been developed to achieve this, they typically suffer from some drawbacks such as time-consuming process, specific device dependence, lack of flexibility, low patterning resolution, and so forth. Herein, we present a general and fast method to functionalize paper sheets and create patterns. The whole modification process can be completed in 10 min and can be applied on various types of paper substrates and other natural materials such as natural fabrics. By our method, many commonly used functional groups can be covalently attached and patterned on paper substrates, while the characteristic features of the original paper substrates, for example, color, transparency, and conductivity, can be perfectly retained after modification to allow these properties to be incorporated into the resultant materials. High-resolution patterns can be created on paper by applying a photomask during the modification or controlling the time of modification to precisely control the functionality at any area on the obtained paper substrates. We also show the potential applications of our method in the fabrication of superhydrophobic coatings and biomaterials.
Keywords: cellulose paper; photochemistry; photopatterning; surface functionalization; thiol−ene.