An improved spectral reflectance estimation method is developed to transform raw camera RGB responses to spectral reflectance. The novelty of our method is to apply a local weighted linear regression model for spectral reflectance estimation and construct the weighting matrix using a Gaussian function in CIELAB uniform color space. The proposed method was tested using both a standard color chart and a set of textile samples, with a digital RGB camera and by ten times ten-fold cross-validation. The results demonstrate that our method gives the best accuracy in estimating both the spectral reflectance and the colorimetric values in comparison with existing methods.