Lanthanide Organic Framework as a Reversible Luminescent Sensor for Sulfamethazine Antibiotics

Kui Ren; Shun-Hua Wu; Xiao-Feng Guo; Hong Wang

doi:10.1021/acs.inorgchem.8b03284

Lanthanide Organic Framework as a Reversible Luminescent Sensor for Sulfamethazine Antibiotics

Inorg Chem. 2019 Apr 1;58(7):4223-4229. doi: 10.1021/acs.inorgchem.8b03284. Epub 2019 Mar 14.

Authors

Kui Ren¹, Shun-Hua Wu¹, Xiao-Feng Guo¹, Hong Wang¹

Affiliation

¹ Key Laboratory of Analytical Chemistry for Biology and Medicine (Ministry of Education), College of Chemistry and Molecular Sciences , Wuhan University , Wuhan 430072 , China.

PMID: 30869880
DOI: 10.1021/acs.inorgchem.8b03284

Abstract

A water-stable two-dimensional lanthanide organic framework, {Eu(BTB)DMF} _n (Eu-MOF; DMF = N, N-dimethylformamide), with two one-dimensional channels was obtained, and its structure was characterized. With changes in the amount of LiOH·H₂O, different sizes of {Eu(BTB)DMF} _n were synthesized. The prepared Eu-MOF powder is easy to disperse in water and exhibits typical Eu red emission. The fluorescence properties showed that Eu-MOF can detect sulfamethzine (SMZ) with high sensitivity and selectivity. Finally, the as-synthesized Eu-MOF was successfully used for the detection of SMZ in surface water by a standard addition method.