Synthesis of oxy-sulfide based nanocomposite catalyst for visible light-driven reduction of Cr(VI)

Abstract

The oxy-sulfide based V₂O₅@(In,Ga)₂(O,S)₃ nanocomposite catalyst, at different weight percentages of V₂O₅, was successfully synthesized via a simplistic procedural route for the detoxification of hazardous Cr(VI). The two pure catalysts were intimately allied and used for visible light-driven reduction of hazardous Cr(VI). The nanocomposite catalysts were characterized to observe the effects of V₂O₅ on crystal phase, morphology, light absorption, catalytic activity, and electrical properties. Compared to all, 40% V₂O₅ loaded nanocomposite catalyst, designated as VOS-2, exhibited the best-reducing capability. It completely reduced toxic Cr(VI) at 2 min under visible light illumination. From the kinetics, it was found that the rate constant of the nanocomposite catalyst was improved by a factor of 3.6 compared to the host nanoflower catalyst. The plausible mechanism of charge transfer process across the interfacial region indicates the diminished recombination probability of photogenerated charge carriers. Therefore, the nanocomposite catalyst is promising for enhanced reduction of Cr(VI) in the Cr-based industrial activities, which is significantly relevant for environmental remediation.

Keywords: Cr(VI) reduction; Nanocomposite catalyst; Photogenerated charge carriers; Photoluminescence spectra; Zeta potential.