A ZnII-Based Metal-Organic Framework with a Rare tcj Topology as a Turn-On Fluorescent Sensor for Acetylacetone

Shu-Li Yao; Sui-Jun Liu; Xue-Mei Tian; Teng-Fei Zheng; Chen Cao; Chun-Yuan Niu; Yong-Qiang Chen; Jing-Lin Chen; Haiping Huang; He-Rui Wen

doi:10.1021/acs.inorgchem.8b03316

A Zn^II-Based Metal-Organic Framework with a Rare tcj Topology as a Turn-On Fluorescent Sensor for Acetylacetone

Inorg Chem. 2019 Mar 18;58(6):3578-3581. doi: 10.1021/acs.inorgchem.8b03316. Epub 2019 Mar 1.

Authors

Affiliations

¹ School of Metallurgy and Chemical Engineering , Jiangxi University of Science and Technology , Ganzhou 341000 , Jiangxi Province , P. R. China.
² College of Chemistry and Chemical Engineering , Jinzhong University , Jinzhong 030619 , Shanxi Province , P. R. China.

PMID: 30821447
DOI: 10.1021/acs.inorgchem.8b03316

Abstract

A Zn^II-based metal-organic framework (MOF) with a rare tcj topology has been solvothermally synthesized and displays relatively good thermal and chemical stabilities. Interestingly, the MOF can sensitively and selectively sense acetylacetone (acac) via a fluorescence enhancement effect with a detection limit of 0.10 ppm and good reusability, which demonstrates the first example of a MOF-based turn-on fluorescent sensor for acac.