Enhanced photoelectrochemical hydrogen generation in neutral electrolyte using non-vacuum processed CIGS photocathodes with an earth-abundant cobalt sulfide catalyst

Mingqing Wang; Yung-Shan Chang; Chun-Wen Tsao; Mei-Jing Fang; Yung-Jung Hsu; Kwang-Leong Choy

doi:10.1039/c8cc09426h

Enhanced photoelectrochemical hydrogen generation in neutral electrolyte using non-vacuum processed CIGS photocathodes with an earth-abundant cobalt sulfide catalyst

Chem Commun (Camb). 2019 Feb 21;55(17):2465-2468. doi: 10.1039/c8cc09426h.

Authors

Mingqing Wang¹, Yung-Shan Chang², Chun-Wen Tsao², Mei-Jing Fang², Yung-Jung Hsu³, Kwang-Leong Choy¹

Affiliations

¹ UCL Institute for Materials Discovery, University College London, Roberts Building, Malet Place, London, WC1E 7JE, UK. k.choy@ucl.ac.uk.
² Department of Materials Science and Engineering, National Chiao Tung University, Hsinchu 30010, Taiwan. yhsu@cc.nctu.edu.tw.
³ Department of Materials Science and Engineering, National Chiao Tung University, Hsinchu 30010, Taiwan. yhsu@cc.nctu.edu.tw and Center for Emergent Functional Matter Science, National Chiao Tung University, Hsinchu 30010, Taiwan.

PMID: 30734787
DOI: 10.1039/c8cc09426h

Abstract

This work reports the novelty of using eco-friendly and cost-effective non-vacuum Electrostatic Spray-Assisted Vapour Deposited Cu(In,Ga)SSe (CIGS) thin films as photocathodes, combined with the earth abundant cobalt sulfide (Co-S) as a catalyst to accelerate the kinetics of photogenerated electron transfer and hydrogen generation for photoelectrochemical water splitting. CdS and ZnO layers were subsequently deposited on top of the selenised CIGS films to increase the charge separation and lower the charge recombination for the photocathodes. In order to improve the lifetime and scalability of the CIGS photocathode and the other cell components, a photoelectrochemical test was conducted in a neutral electrolyte of 0.5 M Na2SO4 under simulated sunlight (AM 1.5G). Both the photocurrent densities and the onset potentials of the photocathodes were significantly improved by the electrodeposition of the low cost and earth-abundant Co-S catalyst, with a photocurrent density as high as 19.1 mA cm-2 at -0.34 V vs. reversible hydrogen electrode (RHE), comparable with and even higher than that of the control photocathode using rare and precious Pt as a catalyst.