Palladium-Catalyzed Oxidative Allylation of Sulfoxonium Ylides: Regioselective Synthesis of Conjugated Dienones

Org Lett. 2019 Feb 15;21(4):872-875. doi: 10.1021/acs.orglett.8b03606. Epub 2019 Feb 6.

Abstract

The first examples of palladium-catalyzed allylic C-H oxidative allylation of sulfoxonium ylides to afford the corresponding conjugated dienones with moderate to good yields have been established. The features of this novel conversion include mild reaction conditions, wide substrate scope, and excellent regioselectivity.

Publication types

  • Research Support, Non-U.S. Gov't