Lead Pollution and Isotope Tracing of Surface Sediments in the Huainan Panji Coal Mining Subsidence Area, Anhui, China

Bull Environ Contam Toxicol. 2019 Jul;103(1):10-15. doi: 10.1007/s00128-019-02558-5. Epub 2019 Feb 6.

Abstract

In this study, the provenance of anthropogenic lead, a major pollutant of surface sediments, was determined in Huainan Panji coal mining area. The lead concentrations and the pollution degree were investigated by the enrichment factor. Tessier five-step morphology extraction method was used to discuss its potential hazard. By comparing the lead isotope ratios of surface sediments and surrounding potential polluted end-members, the lead isotope ternary mixture model was appropriated to explore the sources and relative contribution fractions. The results showed that: (1) The lead concentrations ranged from 31.44 to 64.07 mg/kg which was mild-moderate pollution. (2) The chemical forms of lead were residue state > iron-manganese oxidation state > exchangeable state > organic state > carbonate state. (3) The anthropogenic lead in surface sediments originated from soil, vehicle exhaust, coal gangue. And the relative contribution fractions were 51.70%, 30.90%, and 17.40%.

Keywords: Coal-mining subsidence area; Isotope ratio; Lead; Surface sediment.

MeSH terms

  • China
  • Coal / analysis
  • Coal Mining
  • Environmental Monitoring / methods*
  • Environmental Pollution / analysis
  • Geologic Sediments / chemistry
  • Isotopes
  • Lead / analysis*
  • Metals, Heavy / analysis
  • Soil / chemistry
  • Soil Pollutants / analysis*
  • Vehicle Emissions / analysis

Substances

  • Coal
  • Isotopes
  • Metals, Heavy
  • Soil
  • Soil Pollutants
  • Vehicle Emissions
  • Lead