Ti-V-C-Based Alloy with a FCC Lattice Structure for Hydrogen Storage

Molecules. 2019 Feb 2;24(3):552. doi: 10.3390/molecules24030552.

Abstract

Here we report a Ti50V50-10 wt.% C alloy with a unique lattice and microstructure for hydrogen storage development. Different from a traditionally synthesized Ti50V50 alloy prepared by a melting method and having a body-centered cubic (BCC) structure, this Ti50V50-C alloy synthesized by a mechanical alloying method is with a face-centered cubic (FCC) structure (space group: Fm-3m No. 225). The crystalline size is 60 nm. This alloy may directly absorb hydrogen near room temperature without any activation process. Mechanisms of the good kinetics from lattice and microstructure aspects were discussed. Findings reported here may indicate a new possibility in the development of future hydrogen storage materials.

Keywords: crystal structure; hydrogen absorbing materials; mechanical alloying; metals and alloys.

MeSH terms

  • Alloys / chemistry*
  • Carbon / chemistry*
  • Hydrogen / chemistry
  • Kinetics
  • Materials Testing
  • Surface Properties
  • Titanium / chemistry*
  • Vanadium / chemistry*

Substances

  • Alloys
  • Vanadium
  • Carbon
  • Hydrogen
  • Titanium