Rapid determination of trace level N-nitrosamine precursors in secondary-treated wastewater by using two dimensional-ion chromatography

Abstract

Nowadays, drinking water treatment involves large usage of chloramines making control of N-nitrosamines formation very challenging. Detecting and removing N-nitrosamine precursors in water is the most effective method to reduce N-nitrosamine formation. Therefore, it is essential to develop methods to detect N-nitrosamine precursors. In this paper, a method based on two-dimensional ion chromatography (2D-IC) is presented for detecting the trace levels of N-nitrosamines precursors, including dimethylamine, trimethylamine, diethylamine, methylethylamine, morpholine and piperidine, in relatively short time with minimized sample preparation. The 2D-IC method exhibits better sensitivity for analytes suffering from matrix interference, by eliminating interfering sample matrix ions, than conventional one-dimensional (1D) IC. Detection limits of the six amines were within the range of 0.035 μg/L to 0.1 μg/L. Excellent linearity was achieved for all the target amines with the method developed. The proposed method in this study was applied in the analysis of real wastewater samples. High recoveries ranging from 91.7 to 109.8% and relative standard deviation of less than 5.3% were obtained. The fully automated and simple method shows high selectivity against interfering metal ions and low detection limits, making routine detection of N-nitrosamines precursors practical.

Keywords: Chloramines; Ion chromatography; N-nitrosamines precursors; Secondary-treated wastewater; Two-dimensional.