We report fabrication and simulation of an F2 glass six-strut suspended core fiber (SCF) with small effective core diameter of 2.5 μm for cylindrical vector (CV) modes generation and propagation. Simulation results show that the fiber has a large effective refractive index difference in the order of 10-4-10-3 between the first higher-order CV modes, including TE01, HE21even and odd and TM01 modes. TE01 and TM01 were experimentally generated and were evaluated as having high purity of 82 percent and 85 percent, respectively. The results demonstrate that the SCF is a competitive waveguide candidate for selectable CV mode generation and propagation.