Synthesis of cosmetic grade TiO2-SiO2 core-shell powder from mechanically milled TiO2 nanopowder for commercial mass production

Abstract

TiO₂ nanoparticles as an active sunscreen ingredient generate reactive oxygen species (ROS) upon UVA irradiation which is cytotoxic, genotoxic and potential to damage the DNA. The health concern and potential risks from TiO₂ can be mitigated by shielding the particles through the suitable coating. Considering the advantages of SiO₂, SiO₂ coated TiO₂ nanoparticles can be a potential material which can replace TiO₂ for thickening, whitening, lubricating, and sunscreen ingredient in cosmetics. This article reports the synthesis of cosmetic grade TiO₂-SiO₂ core-shell nanopowder from mechanically milled TiO₂ nanopowder for commercial mass production. From commercial TiO₂ nanopowder was fabricated through size reduction by nanoset milling. Followed by the fabricated TiO₂ nanopowder coated with SiO₂ through sol-gel technique. A suitable optimum condition was explored for cosmetic grade TiO₂-SiO₂ core-shell nanopowder. Various physical properties and optical properties were analyzed. Synthesized of cosmetic grade TiO₂-SiO₂ core-shell nanopowder found to be at 100 nm size, with a homogeneous SiO₂ coating having UVA protection factor 39 and sun protection factor (SPF) is 42. From the size, safety, and SPF perspective it can be an excellent cosmetic grade powder and from process simplicity perspective it can be commercially viable.

Keywords: Cosmetic grade TiO(2)-SiO(2); Nanopowder; SPF; Sunscreen; UVA protection.