Hydrogen-bonding interactions and magnetic relaxation dynamics in tetracoordinated cobalt(ii) single-ion magnets

Ryoji Mitsuhashi; Satoshi Hosoya; Takayoshi Suzuki; Yukinari Sunatsuki; Hiroshi Sakiyama; Masahiro Mikuriya

doi:10.1039/c8dt04537b

Hydrogen-bonding interactions and magnetic relaxation dynamics in tetracoordinated cobalt(ii) single-ion magnets

Dalton Trans. 2019 Jan 2;48(2):395-399. doi: 10.1039/c8dt04537b.

Authors

Ryoji Mitsuhashi¹, Satoshi Hosoya, Takayoshi Suzuki, Yukinari Sunatsuki, Hiroshi Sakiyama, Masahiro Mikuriya

Affiliation

¹ Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan. mitsuhashi@kwansei.ac.jp.

PMID: 30523349
DOI: 10.1039/c8dt04537b

Abstract

Three tetracoordinated cobalt(ii) complexes with a series of unsymmetrical bidentate ligands were synthesized and crystallographically characterized. Although their static magnetic properties are similar, their dynamic magnetic properties differ drastically depending indirectly on intermolecular hydrogen-bonding interactions.