Organic pollution in PGI and non-PGI lemons and related soils from Italy and Turkey

Nat Prod Res. 2019 Nov;33(21):3089-3094. doi: 10.1080/14786419.2018.1519818. Epub 2018 Nov 23.

Abstract

In this work 67 organic contaminants in Protected Geographical Indication (PGI) and non-PGI Interdonato Lemon pulps, peels, leave and related soils were evaluated by GC/MS-MS. It is possible to highlight that in Italian pulps and peels the residues were under LODs (0.10-10.30 ng·g-1), whereas the leaves showed piperonyl butoxide in 33% of samples (11.76 ± 1.24 ng·g-1) and cypermethrins in 33% of samples (Cypermethrin I, 6.12 ± 0.35 ng·g-1; Cypermethrin II, 8.67 ± 0.48 ng·g-1; Cypermethrin III, 8.90 ± 1.52 ng·g-1; Cypermethrin IV, 12.25 ± 2.46 ng·g-1). Turkish samples were mainly contaminated by piperonyl butoxide: it was revealed in the 33% of pulps (3.35 ± 1.03 ng·g-1), in 100% of peels (23.46 ± 17.69 ng·g-1) and in 100% of leaves (1302.44 ± 527.40 ng·g-1). In both soils a different contamination was detected. This study confirms that the European brand (PGI) of Interdonato Lemon Messina is a valuable instrument for the consumer protection.

Keywords: GC-MS/MS; OCPs; PAH; PCBs; PGI and non-PGI Interdonato lemon; soil.

MeSH terms

  • Citrus / chemistry*
  • Environmental Monitoring / methods
  • Gas Chromatography-Mass Spectrometry
  • Geography
  • Italy
  • Piperonyl Butoxide / analysis
  • Pyrethrins / analysis
  • Soil / chemistry*
  • Soil Pollutants / analysis*
  • Turkey

Substances

  • Pyrethrins
  • Soil
  • Soil Pollutants
  • cypermethrin
  • Piperonyl Butoxide