AC Conductivity and Dielectric Properties of (1- x)(0.94Bi0.5Na0.5TiO₃-0.06BaTiO₃)- x Ta Lead Free Ceramics

J Nanosci Nanotechnol. 2019 Mar 1;19(3):1410-1414. doi: 10.1166/jnn.2019.16191.

Abstract

Piezoelectric ceramics such as Pb(Zr,Ti)O₃ (PZT) are currently used by electronic devices because of their superb properties. Lead-based ceramics has caused a lot of environmental problems due to their toxicity. So, lead-free ceramics have been studied as an alternative method due to the toxicity of lead-based ceramics. Lead-free energy harvesting application (Bi0.5N0.5)TiO₃-BaTiO₃ (BNT-BT), is famous for its excellent piezoelectric and electrical properties. The substitution of BNT-BT and Ta5+ also is very effective in improving the relative dielectric permittivity and electrical properties. Because of the device performance depends on the relative dielectric permittivity, temperature and frequency of ceramic are very important condition. In this study, the electrical and relative dielectric permittivity of substitution of BNT-BT with Ta will be analyzed and AC conductivity depending on temperature and frequency will be shown. Also, it will calculate and analyze activation energy in different ranges of frequency.