Electrical and Magnetic Properties of Barium Hexaferrite Modified Barium Zirconium Titanate Lead-Free Ceramics

Pakpoom Jarupoom; Pharatree Jaita; Supalak Manotham; Thanatep Phatungthane; Komsanti Chokethawai; Chamnan Randorn; Gobwute Rujijanagul

doi:10.1166/jnn.2019.16165

Electrical and Magnetic Properties of Barium Hexaferrite Modified Barium Zirconium Titanate Lead-Free Ceramics

J Nanosci Nanotechnol. 2019 Mar 1;19(3):1276-1282. doi: 10.1166/jnn.2019.16165.

Authors

Pakpoom Jarupoom¹, Pharatree Jaita², Supalak Manotham², Thanatep Phatungthane³, Komsanti Chokethawai², Chamnan Randorn⁴, Gobwute Rujijanagul²

Affiliations

¹ Department of Industrial Engineering, Faculty of Engineering, Rajamangala Univerisity of Technology Lanna, Chiang Mai, 50300, Thailand.
² Department of Physics and Materials Science, Faculty of Science, Chiang Mai University, Chiang Mai, 50200, Thailand.
³ Division of Science, Faculty of Education, Nakhon Phanom University, Nakhon Phanom, 48000, Thailand.
⁴ Department of Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai, 50200, Thailand.

PMID: 30469175
DOI: 10.1166/jnn.2019.16165

Abstract

The (BaZr_0.07Ti_0.93O₃)/x(BaFe₁₂O₁₉); (BZT/xBF) (x = 0, 0.1, 0.5 and 1 mol%) ceramics have been prepared via a solid state reaction process. Effects of BF content on the physical, microstructural, magnetic and electrical properties have been systematically investigated. High density sintered specimens (5.65-5.74 g/cm³) are obtained for all compositions. SEM micrographs show a decrease of grain size value when BF is added. Examination of the dielectric spectra show that the two phase-transition temperatures as observed for pure BZT, merges into a single phase-transition temperature for the added-samples. The addition of BF also improves the magnetic behavior (M-H hysteresis loops) of BZT ceramic and resultes in slight changes in ferroelectric properties. The maximum of remanent magnetization (M_r) of 7.19 emu/g is obtained for the 1 mol% sample.