Platinum Nanosheets between Graphite Layers

Chem Rec. 2019 Jul;19(7):1263-1271. doi: 10.1002/tcr.201800098. Epub 2018 Nov 20.

Abstract

Two-dimensional platinum nanosheets were obtained by the hydrogen reduction of platinum tetrachloride intercalated between graphite layers, the latter was prepared by the treatment of the mixture of platinum tetrachloride and graphite powder under chlorine atmosphere. The size of platinum nanosheets was 1-3 nm in thickness with a width in the range of 5-300 nm. These nanosheets contain a number of hexagonal holes and edges with an angle of 120°. This review discusses the reduction and oxidation behavior of platinum species and structure of platinum nanosheets between graphite layers. The selective hydrogenation catalyzed by these platinum nanosheets entrapped between the graphite layers is also demonstrated.

Keywords: Hydrogenation; Intercalations; Layered compounds; Nanoparticles.

Publication types

  • Review