Polarization-dependent strong coupling between silver nanorods and photochromic molecules

Beilstein J Nanotechnol. 2018 Oct 8:9:2657-2664. doi: 10.3762/bjnano.9.247. eCollection 2018.

Abstract

Active plasmonics is a key focus for the development of advanced plasmonic applications. By selectively exciting the localized surface plasmon resonance sustained by the short or the long axis of silver nanorods, we demonstrate a polarization-dependent strong coupling between the plasmonic resonance and the excited state of photochromic molecules. By varying the width and the length of the nanorods independently, a clear Rabi splitting appears in the dispersion curves of both resonators.

Keywords: Rabi splitting; active plasmonics; photochromic molecules; plasmon; strong coupling.