A new "bicycle helmet"-like copper(ii),sodiumphenylsilsesquioxane. Synthesis, structure and catalytic activity

Alena N Kulakova; Alexey N Bilyachenko; Alexander A Korlyukov; Lidia S Shul'pina; Xavier Bantreil; Frédéric Lamaty; Elena S Shubina; Mikhail M Levitsky; Nikolay S Ikonnikov; Georgiy B Shul'pin

doi:10.1039/c8dt03209b

A new "bicycle helmet"-like copper(ii),sodiumphenylsilsesquioxane. Synthesis, structure and catalytic activity

Dalton Trans. 2018 Nov 13;47(44):15666-15669. doi: 10.1039/c8dt03209b.

Authors

Alena N Kulakova¹, Alexey N Bilyachenko, Alexander A Korlyukov, Lidia S Shul'pina, Xavier Bantreil, Frédéric Lamaty, Elena S Shubina, Mikhail M Levitsky, Nikolay S Ikonnikov, Georgiy B Shul'pin

Affiliation

¹ Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov Str., 28, 119991 Moscow, Russia. bilyachenko@ineos.ac.ru.

PMID: 30378606
DOI: 10.1039/c8dt03209b

Abstract

A new "bicycle helmet"-like copper(ii),sodiumphenylsilsesquioxane Ph12Si12O12(OH)(O-)11Cu5Na(bipy)3(H2O) exhibited high catalytic efficiency in two homogeneous reactions: (i) functionalization of C-H compounds; (ii) formation of benzamides from alcohols.