The analytical features of MP-AES for the determination of Mn in wine were studied as compared with ICP-OES. The optimum spectral line (403.076 nm) of MP-AES was different from that (259.373 nm) of ICP-OES. Significant matrix effect was observed with MP-AES, but not with ICP-OES. A simple and cost-effective MP-AES for the quantitation of Mn in wild grape (Vitis coignetiae) red wines were developed and validated. A standard addition method was used to compensate the matrix effects. The sensitivity of MP-AES was comparable to that of ICP-OES. MP-AES was sensitive, precise, accurate and reliable. The Mn concentration in the wild grape wines was in the range of 502-3627 μg L-1. MP-AES had a distinct drawback of low matrix tolerance. However, MP-AES had a clear advantage of the low running cost due to the use of nitrogen gas generated from air with a nitrogen generator.
Keywords: Cross validation; Korean wine; Manganese; Meoru; Microwave plasma-atomic emission spectroscopy; Validation.
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