Controllable synthesis of metal-organic frameworks with well-defined morphology, composition, and size is of great importance toward understanding their structure-property relationship in various applications. Herein, we demonstrate a general strategy to modulate the relative growth rate of the secondary building units (SBUs) along different crystal facets for the synthesis of Fe-Co, Mn0.5Fe0.5-Co, and Mn-Co Prussian blue analogues (PBAs) with tunable morphologies. The same growth rate of SBUs along the {100}, {110}, and {111} surfaces at 0 °C results in the formation of spherical PBA particles, while the lowest growth rate of SBUs along the {100} surface resulting from the highest surface energy with increasing reaction temperature induces the formation of PBA cubes. Fenton reaction was used as the model reaction to probe the structure-catalytic activity relation for the as-synthesized catalysts. The cubic Fe-Co PBA was found to exhibit the best catalytic performance with reaction rate constant 6 times higher than that of the spherical counterpart. Via density functional theory calculations, the abundant enclosed {100} facets in cubic Fe-Co PBA were identified to have the highest surface energy and favor high Fenton reaction activity.
Keywords: DFT calculation; Fenton reaction; Prussian blue analogue; secondary building units; shape-controlled.