Field-induced slow relaxation of magnetisation in an anionic heterotetranuclear [ZnIIRe] system

Adrián Sanchis-Perucho; Carlos Rojas-Dotti; Nicolás Moliner; José Martínez-Lillo

doi:10.1039/c8dt03728k

Field-induced slow relaxation of magnetisation in an anionic heterotetranuclear [Zn^IIRe] system

Dalton Trans. 2019 Jan 2;48(2):370-373. doi: 10.1039/c8dt03728k.

Authors

Adrián Sanchis-Perucho¹, Carlos Rojas-Dotti, Nicolás Moliner, José Martínez-Lillo

Affiliation

¹ Instituto de Ciencia Molecular (ICMol)/Departament de Química Inorgànica, Universitat de València, c/Catedrático José Beltrán 2, 46980 Paterna, Valencia, Spain. f.jose.martinez@uves.

PMID: 30357217
DOI: 10.1039/c8dt03728k

Abstract

The compound (NBu4)4[ZnII{ReIVCl4(μ-ox)}3] (1) [NBu4+ = tetra-n-butylammonium cation and ox2- = oxalate dianion] is the first example of an oxalato-bridged ZnII system coordinated to a 5d metal ion that exhibits slow relaxation of magnetisation.