A luminescent dicyanidonitridotechnetium(v) core with tridentate ligand coordination sites

Dalton Trans. 2018 Nov 22;47(45):16027-16030. doi: 10.1039/c8dt02935k.

Abstract

A novel, luminescent technetium complex, [TcN(CN)2bpa] (bpa = bis-(2-pyridylmethyl)amine), with tridentate ligand coordination sites was synthesized and characterized. Photoemission with a maximum wavelength at 666 nm was observed in the solid-state at 296 K.