Omniphobic surfaces based on reentrant surface structures repel all liquids, regardless of the surface material, without requiring low-surface-energy coatings. Although omniphobic surfaces have been designed and demonstrated, they can fail during condensation, a phenomenon ubiquitous in both nature and industrial applications. Specifically, as condensate nucleates within the reentrant geometry, omniphobicity is destroyed. Here, we show a nanostructured surface that can repel liquids even during condensation. This surface consists of isolated reentrant cavities with a pitch on the order of 100 nm to prevent droplets from nucleating and spreading within all structures. We developed a model to guide surface design and subsequently fabricated and tested these surfaces with various liquids. We demonstrated repellency to 10 °C below the dew point and showed durability over 3 weeks. This work provides important insights for achieving robust, omniphobic surfaces.
Keywords: condensation; hydrophobic; nucleation; omniphobic; reentrant nanocavity.