Insight into carbamazepine degradation by UV/monochloramine: Reaction mechanism, oxidation products, and DBPs formation

Abstract

UV/monochloramine (NH₂Cl) process has attracted some attention for the elimination of contaminants of emerging concern as a novel advanced oxidation process. However, there is still much uncertainty on the performance and mechanisms of UV/NH₂Cl process because of its complexity and generation of various species of radicals, including NH₂^•, HO^•, Cl^• and other reactive chlorine species (RCS). The mechanism and influence factors of degradation of carbamazepine (CBZ) in the UV/NH₂Cl process were investigated, and a synergistic effect was observed. Degradation of CBZ under all investigated conditions followed pseudo-first order kinetics. The corresponding rate constant increased along with the dosage of NH₂Cl, and was affected significantly by the presence of bicarbonate and natural organic matter. The process has little pH-dependency, while the specific contribution of RCS and HO^• changed with solution pH, and RCS always act as a major contributor to the degradation of CBZ. Eleven byproducts of CBZ were identified and their respective evolution profiles were determined. The participation of UV in chloramination can reduce the formation of nitrogenous DBPs, but promote the formation of carbonaceous DBPs. Furthermore, when influent, sand filtered, and granular activated carbon filtered water was respectively used as background, degradation of CBZ was inhibited to different degree and more disinfection byproducts (DBPs) were generated, compared to deionized water. The electrical energy per order for degradation of CBZ in the UV/NH₂Cl process was also calculated to obtain some preliminary cost information.

Keywords: Application potential; Degradation pathway; Disinfection byproducts; Reactive species; Water treatment.