Synthesis of cyclodextrin polymers containing glutamic acid and their use for the synthesis of Ag nanoparticles

Viviane Costa de Souza; Caio H N Barros; Ljubica Tasic; Iara F Gimenez; Zaine Teixeira Camargo

doi:10.1016/j.carbpol.2018.08.101

Synthesis of cyclodextrin polymers containing glutamic acid and their use for the synthesis of Ag nanoparticles

Carbohydr Polym. 2018 Dec 15:202:11-19. doi: 10.1016/j.carbpol.2018.08.101. Epub 2018 Aug 27.

Authors

Viviane Costa de Souza¹, Caio H N Barros², Ljubica Tasic², Iara F Gimenez¹, Zaine Teixeira Camargo³

Affiliations

¹ Department of Chemistry, Federal University of Sergipe, Av. Marechal Rondon s/n, Cidade Universitária "Prof. José Aloísio de Campos", 491000-000, Sao Cristovao, Sergipe, Brazil.
² Department of Organic Chemistry, Institute of Chemistry, University of Campinas, Cidade Universitária Zeferino Vaz s/n, P.O Box 6154, 13083-970, Campinas, Sao Paulo, Brazil.
³ Department of Chemistry, Federal University of Sergipe, Av. Marechal Rondon s/n, Cidade Universitária "Prof. José Aloísio de Campos", 491000-000, Sao Cristovao, Sergipe, Brazil. Electronic address: zaineteixeira@ufs.br.

PMID: 30286982
DOI: 10.1016/j.carbpol.2018.08.101

Abstract

Crosslinking and functionalizing agents play crucial roles in the properties/applications of cyclodextrin polymers. Here we report the synthesis of water-insoluble cyclodextrin polymers containing l-glutamic acid. In a first route, β-cyclodextrin was crosslinked with citric acid and subsequently functionalized with l-glutamic acid, while a second route involved esterification of β-cyclodextrin with l-glutamic acid, catalyzed by tin octoate. Combined evaluation by FTIR, ¹³C CP/MAS NMR and elemental analysis indicated that the sample from the first route had the largest fraction of glutamic acid. Sorption tests with methyl orange showed that the cyclodextrin cavities were slightly more available in the polymer obtained through the second route. Samples were employed as reductant and stabilizer for fast and easy synthesis of silver nanoparticles at room temperature. Brief UV irradiation was sufficient for samples produced by the first route.

Keywords: Cyclodextrin polymers; Esterification; Nanosponges; Plasmonic nanoparticles; Silver nanoparticles; Tin octoate.