Photolysis is considered one of the most important mechanisms for the degradation of pharmaceuticals. Photodecomposition processes to remove pharmaceuticals in water treatment presently use artificial UV light incorporated in advanced oxidation processes. However, UV lighting devices consume a substantial amount of energy and have high operational costs. To develop low energy treatment systems and make good use of abundant sunlight, a natural energy resource as a green technology is needed. As such, a system that combines sunlight focusing, solar tracking and continuous reaction was designed and constructed in the present study, and its application potential as a pharmaceutical water treatment option was tested. Two representative photolabile pharmaceuticals, ciprofloxacin and sulfamethoxazole, were chosen as the target pollutants. The results indicate that the sunlight-focusing system consisting of a UV-enhancing-coated parabolic receiver can concentrate solar energy effectively and hence result in a more than 40% improvement in the direct photolysis efficiency of easily photoconvertible ciprofloxacin. The sunlight-focusing coupled with a solar tracker (SFST) system can improve the sunlight-focusing efficiency by more than 2-fold, thus leading to the maximization of the efficient use of solar energy. Sulfamethoxazole, which is difficult to photoconvert, was successfully degraded by more than 60% compared to direct photolysis through the designed SFST system in the presence of persulfate. The treatment system exhibited good and consistent performance during clear and cloudy days of summer. It is proven that the UV-enhanced coated SFST system with the addition of persulfate indeed has development potential for application in the degradation of pharmaceuticals in water.
Keywords: Antibiotics; Natural photolysis; Persulfate; Photodecomposition; Sunlight-focusing and solar tracking system.
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