Synthesis of the novel MOF hcp UiO-66 employing ionic liquids as a linker precursor

Matthias Ermer; Julian Mehler; Martin Kriesten; Yamini S Avadhut; Peter S Schulz; Martin Hartmann

doi:10.1039/c8dt02999g

Synthesis of the novel MOF hcp UiO-66 employing ionic liquids as a linker precursor

Dalton Trans. 2018 Oct 23;47(41):14426-14430. doi: 10.1039/c8dt02999g.

Authors

Matthias Ermer¹, Julian Mehler, Martin Kriesten, Yamini S Avadhut, Peter S Schulz, Martin Hartmann

Affiliation

¹ Erlangen Catalysis Resource Center (ECRC), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Egerlandstr. 3, 91058 Erlangen, Germany. martin.hartmann@fau.de.

PMID: 30272068
DOI: 10.1039/c8dt02999g

Abstract

By using a terephthalate containing ionic liquid, a new metal-organic framework, hcp UiO-66, comprising (Zr12O8(OH)14) double clusters and terephthalate ligands has been synthesized. The hydrothermal synthesis of hcp UiO-66 might help to establish metal-organic frameworks for industrial scale applications.