Electrokinetic effects in nematic suspensions: Single-particle electro-osmosis and interparticle interactions

Phys Rev E. 2018 Aug;98(2-1):022703. doi: 10.1103/PhysRevE.98.022703.

Abstract

Electrokinetic phenomena in a nematic suspension are considered when one or more dielectric particles are suspended in a liquid crystal matrix in its nematic phase. The long-range orientational order of the nematic constitutes a fluid with anisotropic properties. This anisotropy enables charge separation in the bulk under an applied electric field, and leads to streaming flows even when the applied field is oscillatory. In the cases considered, charge separation is seen to result from director field distortions in the matrix that are created by the suspended particles. We use a recently introduced electrokinetic model to study the motion of a single-particle hyperbolic hedgehog pair. We find this motion to be parallel to the defect-particle center axis, independent of field orientation. For a two-particle configuration, we find that the relative force of electrokinetic origin is attractive in the case of particles with perpendicular director anchoring, and repulsive for particles with tangential director anchoring. The study reveals large scale flow properties that are respectively derived from the topology of the configuration alone and from short scale hydrodynamics phenomena in the vicinity of the particle and defect.