Cobalt-Pincer Complexes in Catalysis

Chemistry. 2019 Jan 2;25(1):122-143. doi: 10.1002/chem.201803016. Epub 2018 Dec 6.

Abstract

Non-noble metal catalysts based on pincer type compounds are of special interest for organometallic chemistry and organic synthesis. Next to iron and manganese, currently cobalt-pincer type complexes are successfully applied in various catalytic reactions. In this review the recent progress in (de)hydrogenation, transfer hydrogenation, hydroboration and hydrosilylation as well as dehydrogenative coupling reactions using cobalt-pincer complexes is summarised.

Keywords: (de)hydrogenation; bond formation; cobalt; homogeneous catalysis; pincer complex; transfer hydrogenation.

Publication types

  • Review