Abstract
A dearomatized PN3P*-nickel hydride complex has been prepared using an oxidative addition process. The first nickel-catalyzed hydrosilylation of CO2 to methanol has been achieved, with unprecedented turnover numbers. Selective methylation and formylation of amines with CO2 were demonstrated by such a PN3P*-nickel hydride complex, highlighting its versatile functions in CO2 reduction.
MeSH terms
-
Amines / chemical synthesis
-
Amines / chemistry
-
Carbon Dioxide / chemistry*
-
Catalysis
-
Coordination Complexes / chemical synthesis
-
Coordination Complexes / chemistry*
-
Methanol / chemical synthesis
-
Methylation
-
Nickel / chemistry*
-
Organophosphorus Compounds / chemistry
-
Oxidation-Reduction
-
Silanes / chemistry
Substances
-
Amines
-
Coordination Complexes
-
Organophosphorus Compounds
-
Silanes
-
Carbon Dioxide
-
Nickel
-
Methanol