Franck-Condon picture of incoherent neutron scattering

Proc Natl Acad Sci U S A. 2018 Sep 18;115(38):9450-9455. doi: 10.1073/pnas.1718720115. Epub 2018 Aug 30.

Abstract

A spectroscopic interpretation of incoherent neutron scattering experiments is presented which is based on Franck-Condon-type probabilities for scattering-induced transitions between quantum states of the target. The resulting expressions for the scattering functions enable an energy landscape-oriented analysis of neutron scattering spectra as well as a physical interpretation of Van Hove's space-time correlation functions in the quantum regime that accounts for the scattering kinematics. They suggest moreover a combined analysis of quasielastic and elastic scattering that become inseparable for complex systems with slow power-law relaxation.

Keywords: Van Hove theory; complex systems; energy landscapes; neutron scattering theory; quasielastic neutron scattering.