A stable 3,5-diphenyl-1,2-disilabenzene was selectively synthesized by the reaction between the isolable disilyne TbbSi[triple bond, length as m-dash]SiTbb (Tbb = 2,6-[CH(SiMe3)2]2-4-t-Bu-phenyl) with phenylacetylenes. Its molecular structure and physical properties were examined and compared to those of the 1,2-disilabenzene that was obtained from the reaction between TbbSi[triple bond, length as m-dash]SiTbb and acetylene. Moreover, a plausible formation mechanism for this reaction is discussed.